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The Reactivity and Properties of Dihapto-Coordinated Phenols

Zottig, Victor Enrico
Format
Thesis/Dissertation; Online
Author
Zottig, Victor Enrico
Advisor
Harman, Dean
Hoffman, Paul
Abstract
Coordination of phenol by the electron rich metal fragment {TpW(NO)(PMe 3 )} causes an enol to ketone tautomerization. The structural change of the phenol has a dramatic effect on the observed reactivity. The regioand stereochemistry of subsequent additions is influenced both sterically and electronically by the metal fragment. Note: Abstract extracted from PDF text
Language
English
Published
University of Virginia, Department of Chemistry, PHD, 2011
Published Date
2011-08-01
Degree
PHD
Collection
Libra ETD Repository
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