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Laying the Groundwork for a Tantalum Dearomatization Agent

Nichols-Nielander, Adam Christopher Milan
Format
Thesis/Dissertation; Online
Author
Nichols-Nielander, Adam Christopher Milan
Advisor
Harman, Dean
Abstract
Chapter 1 provides a brief description of the synthesis of the -basic dearomatization agents {Os(NH3)5}, {TpRe(CO)L} (L=tBuNC, PMe3, py, MeIm, and NH3) and {TpW(NO)(PMe3)}. It also submits a theoretical explanation for the phenomenon of dearomatization via back bonding. The basic principles for the synthesis of a dearomatization agent that have been derived from these past syntheses are discussed in the context of the characteristics that we hoped to design into a new tantalum based dearomatizing metal fragment. Note: Abstract extracted from PDF text
Language
English
Published
University of Virginia, Department of Chemistry, MS, 2010
Published Date
2010-08-01
Degree
MS
Collection
Libra ETD Repository
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